Acta Crystallographica Section E (Aug 2012)

Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ2N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ3O1,O1′:O3]nickel(II)]

  • Peng Zhang,
  • Yu-Jie Liu,
  • Kai-Hui Li,
  • Guang-Rui Yang,
  • Chong-Zhen Mei

DOI
https://doi.org/10.1107/S1600536812031108
Journal volume & issue
Vol. 68, no. 8
pp. m1058 – m1059

Abstract

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In the title compound, [Ni(C20H13O5P)(C12H10N2)(H2O)]n, the NiII cation is coordinated by three O atoms from two 5-(diphenylphosphinoyl)isophthalate anions, two N atoms from two 1,2-bis(pyridin-4-yl)ethene ligands and one water molecule in a distorted octahedral geometry. Both 1,2-bis(pyridin-4-yl)ethene and 5-(diphenylphosphinoyl)isophthalate bridge the NiII cations to form polymeric layers parallel to (001). In the crystal, O—H...O hydrogen bonding links layers into a three-dimensional supramolecular structure.