Effect of Al2O3 addition on the non-isothermal crystallization kinetics and long-term stability of BCABS sealing glass for IT-SOFCs

Abstract

Abstract Owing to adjustable thermal expansion performance, BaO–CaO–Al2O3–B2O3–SiO2 (BCABS) glass has a promising commercialization prospect for intermediate temperature-solid oxide fuel cells (IT-SOFCs) sealing. Herein, Al2O3 with two different contents was added into the same glass formulation, referred to as A and B glass, respectively. In terms of the non-isothermal crystallization kinetic behavior, the effect of Al2O3 as the unique intermediate was innovatively studied on the long-term performance of BCABS sealing glass. After the heat treatment at 1023 K for 100 h, the change of the network structure and the expansion coefficient of the glass were characterized. The results showed that the addition of Al2O3 as a network forming body could enhance the structure of glass, and increase the activation energy for glass transition, which could effectively inhibit the crystallization ability of sealing glass. Therefore, the B glass with the higher Al2O3 content showed the better long-term sealing ability, which was greatly beneficial for IT-SOFCs sealing.

Keywords

• intermediate temperature-solid oxide fuel cell (IT-SOFC)
• BaO–CaO–Al2O3–B2O3–SiO2 (BCABS) sealing glass
• Al2O3
• non-isothermal crystallization kinetics
• long-term stability