Acta Crystallographica Section E (Apr 2013)

N-(2-Methoxybenzyl)-9-(oxolan-2-yl)-9H-purin-6-amine

  • Zdeněk Trávníček,
  • Igor Popa,
  • Zdeněk Dvořák,
  • Pavel Štarha

DOI
https://doi.org/10.1107/S1600536813007721
Journal volume & issue
Vol. 69, no. 4
pp. o588 – o588

Abstract

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The title compound, C17H19N5O2, features an almost planar purine skeleton (r.m.s. deviation = 0.009 Å) substituted by a tetrahydrofuran ring, which adopts an envelope conformation. The purine and benzene rings subtend a dihedral angle of 66.70 (3)°. In the crystal, pairs of N—H...N hydrogen bonds connect adjacent molecules into inversion dimers. C—H...N, C—H...O, C—H...π and π–π interactions [pyrimidine ring centroid–centroid distance = 3.3909 (1) Å] connect the dimers into a three-dimensional architecture.