Raman Spectroscopic Study of Coal Samples during Heating

Abstract

Raman spectroscopy can be used to record the characteristic spectra of carbonaceous materials. The D and G bands are the most popular and most important spectral characteristics when discussing carbonaceous materials. In this paper, a Raman spectroscopic study of different coals was first carried out using a 355 nm wavelength laser beam as an excitation source. The spectral parameters of the resultant spectra were evaluated and analyzed. Raman spectral characteristics of different kinds of coals were explored. The high temperature-dependent Raman spectra of the coals were further collected in a temperature range from 298 to 1473 K in order to investigate the transformations of the internal structure of the coals during the pyrolysis process. An abnormal blue shift of the G band occurred at moderate temperature (600−900 K), and the intensity of the G band became weaker at high temperatures, indicating pyrolysis and graphitization of the sample at moderate and high temperature, respectively.

Keywords

• coal
• in-situ raman spectroscopy
• pyrolysis
• characteristic raman bands