Acta Crystallographica Section E (Aug 2011)

Methyl 6-azido-6-deoxy-α-d-galactoside

  • Janice M. H. Cheng,
  • Shivali A. Gulab,
  • Mattie S. M. Timmer,
  • Bridget L. Stocker,
  • Graeme J. Gainsford

DOI
https://doi.org/10.1107/S1600536811025323
Journal volume & issue
Vol. 67, no. 8
pp. o1941 – o1942

Abstract

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The structure of the title compound, C7H13N3O5, was solved using data from a multiple fragment crystal. The galactoside ring adopts a 4C1 chair conformation. In the crystal, the molecules are linked by strong O—H...O hydrogen bonds, which build linkages around the screw axis of the cell in a similar way to the iodo analogue. These C-5 and C-6 packing motifs expand to R22(10), C22(7) and C222(8) motifs, as found in closely related compounds.