Case Studies in Construction Materials (Dec 2024)
Transformative potential: Utilizing Teos-modified mugwort for sustainable construction
Abstract
Exploring innovative materials derived from natural sources holds significant promise in pursuing sustainable construction practices. This study investigates the modification of mugwort (Artemisia dubia Wall.) with TEOS (tetraethyl orthosilicate) and its application as a sustainable reinforcement material in construction applications. It aims to integrate the plant's inherent strength with TEOS-enhanced mechanical properties and assess the feasibility of incorporating TEOS-modified mugwort into a lime-based matrix. The modified mugwort and its lime-based composite characterisation were conducted using FTIR, SEM-EDS, thermogravimetric analysis, compressive strength tests, and nitrogen adsorption analysis. FTIR analysis showcases significant structural enhancements post-modification, corroborated by SEM-EDS findings indicating increased silicon content. Peaks at 2915, 2845, and 1256 cm⁻¹ confirm successful modification with octadecyl amine and Si-C bond integration. Silica-related peaks at 1052, 801, and 456 cm⁻¹ indicate the presence of Si-O-Si structures. SEM analysis observes the presentation of Si as a layer confirming line scan position results, and EDS analysis findings indicate an increased silicon content of 15.16 %. Thermogravimetric analysis of modified samples displayed improved stability at low temperatures and more significant mass loss at high temperatures (72.01 % for modified and 28.91 % for unmodified samples) due to the decomposition of new chemical components. Nitrogen adsorption measurements reveal enhanced porosity in modified mugwort, suggesting diverse applications. The surface area of modified mugwort increased by 85 % compared to unmodified samples. Compressive strength analyses underscore the material's suitability for construction, with modified samples exhibiting denser structures at 8.5 % and higher strength at 13.3 % compared to unmodified samples. Macrostructure analysis further supports this, highlighting enhanced compatibility with binding materials. Overall, modified mugwort emerges as a versatile, eco-friendly reinforcement material with improved mechanical and thermal properties, poised for various applications in sustainable construction.