Powder properties of carbon-based solid acid catalyst for designing cellulose hydrolysis reactor with stirring apparatus

Abstract

The powder properties of a carbon-based solid acid catalyst, an amorphous carbon material bearing SO3H, COOH and OH groups, were investigated for the hydrolysis of cellulose. The Carr flowability and floodability indices, the angle of internal friction (adherence), and the particle size distribution and shape for the powder catalyst were determined. The need to develop a special reactor with a stirring apparatus for the hydrolysis of cellulose was determined based on the Carr flowability index. Insight into the interaction or adherence between the catalyst and crystalline cellulose during the hydrolysis process was gained by measuring the internal friction angle. The optimum moisture content in the catalyst to achieve the maximum adherence was investigated.

Keywords

• Carbon-based solid acid catalyst
• Flowability
• Floodability
• Adherence
• Cellulose hydrolysis