An Effective Flux Framework for Linear Irreversible Heat Engines: Case Study of a Thermoelectric Generator

Abstract

We consider an autonomous heat engine in simultaneous contact with a hot and a cold reservoir and describe it within a linear irreversible framework. In a tight-coupling approximation, the rate of entropy generation is effectively written in terms of a single thermal flux that is a homogeneous function of the hot and cold fluxes. The specific algebraic forms of the effective flux are deduced for scenarios containing internal and external irreversibilities for the typical example of a thermoelectric generator.

Keywords

• thermoelectricity
• nonequilibrium phenomena
• linear irreversible thermodynamics
• effective flux