Latest progress in covalently modified polyoxometalates-based molecular assemblies and advanced materials

Huaiying Zhang; Wan-Lei Zhao; Hongqiang Li; Qinghe Zhuang; Zeqian Sun; Dongyuan Cui; Xuejie Chen; Ao Guo; Xiang Ji; Sai An; Wei Chen; Yu-Fei Song

doi:10.26599/POM.2022.9140011

Polyoxometalates (Dec 2022)

Latest progress in covalently modified polyoxometalates-based molecular assemblies and advanced materials

Huaiying Zhang,
Wan-Lei Zhao,
Hongqiang Li,
Qinghe Zhuang,
Zeqian Sun,
Dongyuan Cui,
Xuejie Chen,
Ao Guo,
Xiang Ji,
Sai An,
Wei Chen,
Yu-Fei Song

Affiliations

Huaiying Zhang: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Wan-Lei Zhao: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Hongqiang Li: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Qinghe Zhuang: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Zeqian Sun: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Dongyuan Cui: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Xuejie Chen: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Ao Guo: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Xiang Ji: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Sai An: ORCiD; State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Wei Chen: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Yu-Fei Song: ORCiD; State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

DOI: https://doi.org/10.26599/POM.2022.9140011
Journal volume & issue: Vol. 1, no. 2
pp. 9140011 – 9140011

Abstract

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Covalently modified polyoxometalates (POMs), which benefit from the synergistic effect between POMs and covalently grafted moieties, have received increasing attention in various fields. Recent studies on covalently modified POMs mainly focus on function-directed POM assemblies. This review summarizes the latest progress (2017–2022) concerning covalently modified POMs from a functional perspective, which can be classified as assembly chemistry, photochemistry, electrochemistry, homogeneous and heterogeneous catalysis, and biological applications. The roles of POMs and covalently grafted moieties in these hybrids, especially the rational design for specific applications, were considered and emphasized.

Published in Polyoxometalates

ISSN: 2957-9821 (Print); 2957-9503 (Online)
Publisher: Tsinghua University Press
Country of publisher: China
LCC subjects: Science: Chemistry: Inorganic chemistry
Website: https://www.sciopen.com/journal/2957-9821

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