Highly Effective Fe-Doped Nano Titanium Oxide for Removal of Acetamiprid and Atrazine under Simulated Sunlight Irradiation

Abstract

Pesticides are widely detected in large quantities in the environment, posing an ecological threat to the human body and ecology. Semiconductor nanomaterials such as nano-titania (nTiO2) have strong photocatalytic degradation efficiency for pollutants. However, the wide bandgap and limited light absorption range inhibit nano-titania’s practical application. Therefore, nTiO2 was modified by Fe3+ doping using the microwave hydrothermal method to improve its photocatalytic performance in this study. Fe-nTiO2 doped with a 1.0% mass ratio was used due to its high photocatalytic performance. Its maximum degradation efficiencies for ACE and ATZ under a 20 W xenon lamp were 88% and 88.5%, respectively. It was found that Fe3+ doping modification distorted the spatial morphology of nTiO2 and shortened the bandgap to facilitate the photocatalytic reaction. The electron paramagnetic resonance results showed that the reactive radicals (1O2, ·OH) produced by photogenerated electrons (e−) and holes (h+) of Fe-nTiO2 were the main active species in the degradation of ACE and ATZ. Additionally, the application of Fe-nTiO2 significantly enhanced the growth of lettuce under sunlight; the degradation efficiencies of ACE and ATZ in lettuce were 98.5% and 100%, respectively. This work provides new insights into the removal of organic contaminants by photocatalysts under sunlight in agriculture.

Keywords

• acetamiprid
• atrazine
• nano titanium oxide
• Fe³⁺-doped
• degradation mechanisms