The extensive application of biodegradable polymers in the food packaging industries was partially limited due to poor barrier performances. In the present work, we investigated the improvement of oxygen barrier performances by means of the deposition of a few nanometres of SiOx coatings on Poly(butylene succinate) (PBS) films. The coated samples produced by the plasma-enhanced chemical vapor deposition technique were tested in terms of morphology and composition of the surface and barrier properties. Barrier performances studied as a function of SiOx thickness were greatly improved and a reduction of at least 99% was achieved for oxygen transmission rate. In order to reduce the formation of residual stress between PBS substrate and SiOx coatings, a proper buffer layer (silicon organic SiOxCyHz) was used.
