Acta Crystallographica Section E (Dec 2011)

1,3-Bis(2-cyanobenzyl)imidazolium bromide

  • Rosenani A. Haque,
  • Safaa A. Ahmed,
  • Zulikha H. Zetty,
  • Madhukar Hemamalini,
  • Hoong-Kun Fun

DOI
https://doi.org/10.1107/S1600536811048951
Journal volume & issue
Vol. 67, no. 12
pp. o3462 – o3462

Abstract

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In the title salt, C19H15N4+·Br−, the central imidazole ring makes dihedral angles of 83.1 (2) and 87.6 (2)° with the terminal benzene rings. The dihedral angle between the terminal benzene rings is 6.77 (19)°; the cyanide substituents have an anti orientation. In the crystal, the cations and anions are linked via C—H...N and C—H...Br hydrogen bonds, forming sheets lying parallel to the ac plane.