Acta Crystallographica Section E (Feb 2013)

4-[Bis(4-fluorophenyl)methyl]-1-[(2E)-3-phenylprop-2-en-1-yl]piperazin-1-ium 3-carboxypropanoate

  • Channappa N. Kavitha,
  • Hemmige S. Yathirajan,
  • Badiadka Narayana,
  • Thomas Gerber,
  • Benjamin van Brecht,
  • Richard Betz

DOI
https://doi.org/10.1107/S1600536813000706
Journal volume & issue
Vol. 69, no. 2
pp. o260 – o261

Abstract

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In the title salt, C26H27F2N2+·C4H5O4−, the piperazine N atom bearing the vinylic substituent is protonated. The piperazine ring adopts a chair conformation. In ther crystal, the succinate monoanions are connected via short O—H...O hydrogen bonds between the carboxylic acid and carboxylate groups into undulating chains extending along [001] and the flunarizinium monocations are attached to these chains via N+—H...O− hydrogen bonds. C—H...O interactions connect these chains into a three-dimensional network. The shortest centroid–centroid distance of 3.7256 (10) Å was found between one of the fluorinated benzene rings and the non-fluorinated phenyl ring in the neighbouring molecule related by a glide plane.