Química Nova (Jan 2012)

Simulação do intemperismo natural de pilhas zinco-carbono e alcalinas

  • Sílvio Carrielo Câmara,
  • Júlio Carlos Afonso,
  • Lilian Irene Dias da Silva,
  • Nelma Nogueira Domingues,
  • Arnaldo Alcover Neto

DOI
https://doi.org/10.1590/S0100-40422012000100016
Journal volume & issue
Vol. 35, no. 1
pp. 82 – 90

Abstract

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Spent alkaline and Zn-C batteries were placed in seawater, rainwater or landfill leachate at room temperature for up 30 days in order to simulate natural weathering. After the experiments pH and electrical conductivity of the liquid were measured. The precipitate formed and the filtrate were submitted to metal analysis by ICP-OES. Seawater is the most corrosive medium, followed by landfill leachate. Pb, Cd and Hg were mainly in the filtrate. Fe, Mn and Zn were generally dominant in the precipitate. Na and K account for the electrical conductivity and are good indicators of the corrosion stage of the batteries.

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