Summary: Direct and stable conversion of CO2 to aromatics (CTA) is an attractive route for reducing CO2 emissions. However, due to the chemical inertness of CO2, direct CTA reaction with high aromatics selectivity is still challenging. In this work, a tandem catalyst Zn0.1Ti0.9Ox/HZSM-5 with appropriate density and strength of acid sites exhibits a high aromatics selectivity of 67.2% and long-term stability over 100 h. Furthermore, the total selectivity of benzene, toluene, and xylene achieves 24.1% over Zn0.1Ti0.9Ox/HZSM-5 with a modified hydrophilic surface. In addition, the CTA via the formate route has been determined in this reaction system.
