International Journal of Biomaterials (Jan 2009)
Charge Transport Mechanism in Thin Cuticles Holding Nandi Flame Seeds
Abstract
Metal-sample-metal sandwich configuration has been used to investigate DC conductivity in 4 πm thick Nandi flame [Spathodea campanulata P. Beauv.] seed cuticles. π½-π characteristics showed ohmic conduction at low fields and space charge limited current at high fields. Charge mobility in ohmic region was 4.06Γ10β5(m2Vβ1sβ1). Temperature-dependent conductivity measurements have been carried out in the temperature range 320 K 450 K. Activation energy within a temperature of 320 Kβ440 K was about 0.86 eV. Variable range hopping (VRH) is the main current transport mechanism at the range of 330β440 K. The VRH mechanism was analyzed based on Mott theory and the Mott parameters: density of localized states near the Fermi-level N(πΈπΉ)β9.04Γ1019(eVβ1cmβ3) and hopping distance π β1.44Γ10β7 cm, while the hopping energy (π) was in the range of 0.72 eVβ0.98 eV.