Pretreatment of Lithium Ion Batteries for Safe Recycling with High-Temperature Discharging Approach

Abstract

The ongoing transition toward electric vehicles is a major factor in the exponential rise in demand for lithium-ion batteries (LIBs). There is a significant effort to recycle battery materials to support the mining industry in ensuring enough raw materials and avoiding supply disruptions, so that there will be enough raw materials to produce LIBs. Nevertheless, LIBs that have reached the end of their useful lives and are sent for recycling may still have some energy left in them, which could be dangerous during handling and processing. Therefore, it is important to conduct discharge pretreatment of LIBs before dismantling and crushing them, especially in cases where pyrometallurgical recycling is not used. Electrochemical discharge in conducting solutions has been commonly studied and implemented for this purpose, but its effectiveness has yet to be fully validated. Non-electrochemical discharge has also been researched as a potentially cleaner and more efficient discharge technology at the same time. This article presents a non-electrochemical discharge process by completely draining the energy from used batteries before recycling. A comprehensive investigation of the behavior of LIBs during discharge and the amount of energy remaining after fully discharging the battery at different temperatures is analyzed in this work. According to the experimental findings, completely discharging the battery at higher temperatures results in a reduced amount of residual energy in the battery. This outcome holds great importance in terms of safe and environmentally friendly recycling of used LIBs, emphasizing that safety and environmentally friendly recycling must go hand in hand with a cost-effective and sustainable solution.

Keywords

• spent LIBs
• discharge pretreatment
• remaining energy
• clean discharge
• recycling