Acta Crystallographica Section E (Dec 2011)

Ethyl (Z)-4-ferrocenyl-2-(4-hydroxyanilino)-4-oxobutenoate

  • Bei-Bei Zhu,
  • Yao-Cheng Shi,
  • Feng-Min Zhang,
  • Li-Min Yuan,
  • Qian-Kun Li

DOI
https://doi.org/10.1107/S1600536811047763
Journal volume & issue
Vol. 67, no. 12
pp. m1761 – m1761

Abstract

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In the title compound, [Fe(C5H5)(C17H16NO4)], the O=C—C=C—N mean plane is twisted with respect to the mean planes of the benzene and substituted cyclopentadienyl rings by 44.2 (2) and 13.8 (3)°, respectively. Furthermore, the O=C—C=C—N mean plane and the O=C—O(ester) plane make a dihedral angle of 55.5 (6)°. Consistent with this large dihedral angle, the linking C—C bond [1.507 (6) Å] does not show any (delocalized) double-bond character.