Propylene Polymerization and Deactivation Processes with Isoselective {Cp/Flu} Zirconocene Catalysts

Abstract

Industrially relevant single-site precatalysts used to produce isotactic polypropylene (iPP) include C2-symmetric {SBI} and C1-symmetric {Cp/Flu} complexes of group 4 metals. While the latter can produce iPPs with a higher degree of isotacticity, they also suffer from poor productivity compared to their {SBI} counterparts. Several causes for this trend have been suggested—2,1-Regioinsertions are frequently pointed out, as they are suspected to drive the catalyst into a dormant state. While this event does not seem to significantly impact the productivity of {SBI} systems, the influence of these regioerror is poorly documented for isoselective {Cp/Flu} precatalysts. To address this issue, new Ph2X(Cp)(Flu) (Ph2X = Ph2C, FluC, Ph2Si) proligands (2a–k) and some of the corresponding dichlorozirconocenes (3a–h,k) were synthesized. These new compounds were characterized and tested in homogeneous propylene polymerization at 60 °C and the amounts of regioerrors in the resulting polymers were examined by 13C NMR spectroscopy. A possible correlation between poor productivity and a high number of regioerrors was investigated and is discussed. Furthermore, a C-H activation process in the bulky nBu3C substituent upon activation of 4c (the dimethylated analog of 3c) by B(C6F5)3 has been evidenced by NMR; DFT calculations support this C-H activation as a deactivation mechanism.

Keywords

• zirconocene
• polymerization
• polypropylene
• regiocontrol
• stereocontrol
• deactivation