Preparation of ZnO Nanorods/Graphene Composite Anodes for High-Performance Lithium-Ion Batteries

Abstract

ZnO is a promising anode material for lithium-ion batteries (LIBs); however, its practical application is hindered primarily by its large volume variation upon lithiation. To overcome this drawback, we synthesized ZnO/graphene composites using the combination of a simple hydrothermal reaction and spray drying. These composites consisted of well-dispersed ZnO nanorods anchored to graphene. The folded three-dimensional graphene spheres provided a high conductivity, high surface area, and abundant defects. LIB with an anode composed of our novel ZnO/graphene material demonstrated a high initial discharge capacity of 1583 mAh g−1 at 200 mA g−1.

Keywords

• ZnO/graphene composites
• anode
• lithium-ion battery