Nature Communications (Jul 2022)
Palladium catalyzed radical relay for the oxidative cross-coupling of quinolines
- Xiaorui Zhao,
- Xiaojuan Zhu,
- Kang Wang,
- Junqian Lv,
- Shangjun Chen,
- Guohua Yao,
- Junyu Lang,
- Fei Lv,
- Yinghui Pu,
- Ruoou Yang,
- Bingsen Zhang,
- Zheng Jiang,
- Ying Wan
Affiliations
- Xiaorui Zhao
- The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
- Xiaojuan Zhu
- The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
- Kang Wang
- The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
- Junqian Lv
- The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
- Shangjun Chen
- The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
- Guohua Yao
- The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
- Junyu Lang
- School of Physical Science and Technology, Shanghai Tech University
- Fei Lv
- The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
- Yinghui Pu
- Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
- Ruoou Yang
- State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology
- Bingsen Zhang
- Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
- Zheng Jiang
- Shanghai Synchrotron Radiation Facility, Zhangjiang National Lab, Shanghai Advanced Research Institute, Chinese Academy of Sciences
- Ying Wan
- The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
- DOI
- https://doi.org/10.1038/s41467-022-31967-0
- Journal volume & issue
-
Vol. 13,
no. 1
pp. 1 – 11
Abstract
Traditional approaches for transition-metal catalyzed oxidative cross-coupling reactions rely on sp 2-hybridized starting materials. Here the authors report a heterogeneous Pd-catalyzed radical relay method for the conversion of a heteroarene C(sp 3)–H bond into ethers.
