On the mechanism of high-temperature superconductivity in hydrogen sulfide at 200 GPa: Transition into superconducting anti-adiabatic state in coupling to H-vibrations

Abstract

It has been shown that the adiabatic electronic structure of the superconducting phase of sulfur hydride at 200 GPa is unstable toward the vibration motion of H-atoms. A theoretical study indicates that in coupling to H-vibrations, the system undergoes a transition from adiabatic into a stabilized anti-adiabatic multi-gap superconducting state at a temperature that can reach 203 K. Keywords: Superconductivity of sulfur hydride, Electron–phonon coupling in superconductors, Anti-adiabatic theory of superconductivity