Materials Research Letters (Aug 2018)

Chemical complexity induced local structural distortion in NiCoFeMnCr high-entropy alloy

  • Fuxiang Zhang,
  • Yang Tong,
  • Ke Jin,
  • Hongbin Bei,
  • William J. Weber,
  • Ashfia Huq,
  • Antonio Lanzirotti,
  • Matt Newville,
  • Darren C. Pagan,
  • J. Y. P. Ko,
  • Yanwen Zhang

DOI
https://doi.org/10.1080/21663831.2018.1478332
Journal volume & issue
Vol. 6, no. 8
pp. 450 – 455

Abstract

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In order to study chemical complexity-induced lattice distortion in high-entropy alloys, the static Debye–Waller (D-W) factor of NiCoFeMnCr solid solution alloy is measured with low temperature neutron diffraction, ambient X-ray diffraction, and total scattering methods. The static atomic displacement parameter of the multi-element component alloy at 0 K is 0.035–0.041 Å, which is obvious larger than that of element Ni (∼ 0 Å). The atomic pair distance between individual atoms in the alloy investigated with extended X-ray absorption fine structure (EXAFS) measurements indicates that Mn has a slightly larger bond distance (∼0.4%) with neighbor atoms than that of others.

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