Thermogravimetry Applied for Investigation of Coke Formation in Ethanol Conversion over Heteropoly Tungstate Catalysts

Abstract

Thermogravimetric analysis (TGA) was used to evaluate the thermal stability and the amount of coke deposition resulting from the deactivation of catalysts during ethanol dehydration reaction in a fixed bed continuous flow reactor. In this study, a series of catalysts containing 30% of Pd doped and pure 12-tungstophosphoric acid and its insoluble Cs2.5H0.5PW12O40 salt supported on SBA-15 were prepared. The catalytic efficiency of ethanol dehydration reaction was also evaluated. Two types of coke are identified from the TPO (Temperature programmed oxidation) profiles and assigned to the coke precursor and hard coke, respectively. The results indicate that cesium salts reduced the formation of hard coke. The amount of total coke formed was significantly reduced by supporting the catalysts on mesoporous SBA-15 molecular sieves.

Keywords

• heteropoly acid
• thermogravimetric analysis
• ethanol conversion
• coke formation
• catalyst stability
• cesium salts