MOFs-Derived Nano-CuO Modified Electrode as a Sensor for Determination of Hydrazine Hydrate in Aqueous Medium

Abstract

It very important to be able to efficiently detect hydrazine hydrate in an aqueous medium due to its high toxicity. Here, we have proposed a new idea: to construct a sensor for the rapid determination of hydrazine hydrate based on the nano-CuO derived by controlled pyrolysis of HKUST-1 [Cu3(BTC)2(H2O)3]. The as-prepared CuO at 400 °C possesses a uniform appearance with nano-structure via SEM images, and the nano-CuO-400 has exhibited excellent electrocatalytic activity towards hydrazine oxidation. Amperometric i-t curves shows the peak current as linearly proportional to the hydrazine concentration within 1.98−169.3 μmol L−1 and 232−2096 μmol L−1 with the detection limit of 2.55 × 10−8 mol L−1 and 7.01 × 10−8 mol L−1, respectively. Moreover, the sensor constructed in the experiment shows good selectivities, and it is feasible to determining actual water samples.

Keywords

• metal-organic frameworks
• pyrolysis derivatives
• electrochemical sensor
• hydrazine hydrate