Nature Communications (Oct 2022)
Real-space measurement of orbital electron populations for Li1-x CoO2
- Tongtong Shang,
- Dongdong Xiao,
- Fanqi Meng,
- Xiaohui Rong,
- Ang Gao,
- Ting Lin,
- Zhexin Tang,
- Xiaozhi Liu,
- Xinyan Li,
- Qinghua Zhang,
- Yuren Wen,
- Ruijuan Xiao,
- Xuefeng Wang,
- Dong Su,
- Yong-Sheng Hu,
- Hong Li,
- Qian Yu,
- Ze Zhang,
- Vaclav Petricek,
- Lijun Wu,
- Lin Gu,
- Jian-Min Zuo,
- Yimei Zhu,
- Ce-Wen Nan,
- Jing Zhu
Affiliations
- Tongtong Shang
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Dongdong Xiao
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Fanqi Meng
- State Key Lab of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University
- Xiaohui Rong
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Ang Gao
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Ting Lin
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Zhexin Tang
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Xiaozhi Liu
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Xinyan Li
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Qinghua Zhang
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Yuren Wen
- School of Materials Science and Engineering, University of Science and Technology Beijing
- Ruijuan Xiao
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Xuefeng Wang
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Dong Su
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Yong-Sheng Hu
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Hong Li
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Qian Yu
- Department of Materials Science and Engineering, Center of Electron Microscopy and State Key Laboratory of Silicon Materials, Zhejiang University
- Ze Zhang
- Department of Materials Science and Engineering, Center of Electron Microscopy and State Key Laboratory of Silicon Materials, Zhejiang University
- Vaclav Petricek
- Institute of Physics, Academy of Sciences of the Czech Republic
- Lijun Wu
- Condensed Matter Physics and Materials Science Division, Brookhaven National Laboratory
- Lin Gu
- Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences
- Jian-Min Zuo
- Department of Materials Science and Engineering, University of Illinois at Urbana Champaign
- Yimei Zhu
- Condensed Matter Physics and Materials Science Division, Brookhaven National Laboratory
- Ce-Wen Nan
- State Key Lab of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University
- Jing Zhu
- Beijing National Center for Electron Microscopy, Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University
- DOI
- https://doi.org/10.1038/s41467-022-33595-0
- Journal volume & issue
-
Vol. 13,
no. 1
pp. 1 – 8
Abstract
Experimentally probing the orbital population is highly desirable to resolve the redox mechanism of cathodes materials. Here the authors quantify the orbital populations of Co and O in LiCoO2 and identify the ligand-to-metal charge transfer.
