Vertical Distribution, Diurnal Evolution, and Source Region of Formaldehyde During the Warm Season Under Ozone-Polluted and Non-Polluted Conditions in Nanjing, China

Abstract

Formaldehyde (HCHO), a key volatile organic compound (VOC) in the atmosphere, plays a crucial role in driving photochemical processes. Satellite-based observations of column concentrations of HCHO and other gaseous pollutants (e.g., NO2) have generally been used in previous studies to elucidate the mechanisms behind secondary organic aerosol (SOA) and ozone (O3) formation. This study aimed to investigate the characteristics of HCHO by retrieving its vertical profile over Nanjing during the warm season (May–June 2022) and analyzing the diurnal variation in vertical distribution and potential source regions on non-polluted (MDA8 O3 −3, NO3P) and O3-polluted (MDA8 O3 ≥ 160 μg m−3, O3P) days. Under both conditions, HCHO was primarily concentrated below 1.5 km altitude, with average vertical profiles displaying similar Boltzmann-like distributions. However, HCHO concentrations on O3P days were 1.2–1.6 times higher than those on non-polluted days at the same altitude below 1.5 km. Maximum HCHO concentrations occurred in the afternoon, while the peak value in the 0.1–0.4 km layers was reached around noon (~11:00 a.m.). The variation rates (VR) of HCHO in the 0.3–1.2 km altitudes had a maximum on O3P days (approximately 0.33 ppbv h−1), and were significantly higher (p 3P days (0.14–0.20 ppbv h−1). The analysis of footprints showed that HCHO concentrations were jointly influenced by the upstream region and the surroundings of the study site. The study results improve the understanding of the vertical distribution and potential source regions of HCHO.

Keywords

• formaldehyde
• vertical profile
• diurnal evolution
• potential source region
• MAX-DOAS