Preparation and characterization of selective electrode for determination of copper ion(II)

Abstract

Achemically modified carbon paste electrode with diphenyl carbazide the potentiometric determination of Cu(II) is demonstrated. The electrode exhibits linear response to Cu(II) over a wide concentration range (9.2×10−7-5.0×10−1) with Nernstian slope of 30±0.15 mV per decade. It has a response time of about 40 s and can be used for a period of two months with good reproducibility. The detection limit of this electrode was 7.0×10−7 M. The proposed electrode shows a very good selectivity for Cu(II) over a wide variety of metal ions. This chemically modified carbon paste electrode was successfully used for the determination of Cu(II) in various water samples solution and pharmaceutical formulation

Keywords

• diphenyl carbazide
• copper
• potentiometric
• method validation