High removal of methylene blue and methyl violet dyes from aqueous solutions using efficient biomaterial byproduct

Abstract

Dyes are among the toxic contaminants that significantly impact water ecosystems. A biomaterial prepared from Zizyphus Spina-Christi seed (ZSCS) to remove methylene blue (MB) and methyl violet (MV) from an aqueous solution was investigated. Several techniques have been used, including FTIR, SEM, EDX, XPS, and TGA, to characterize the physical and chemical properties of ZSCS. The effect of various parameters such as pH, adsorbent dosage, contact time, temperature, and initial dye concentration on the adsorption process were studied. The ZSCS adsorbent showed efficient MB and MV dye adsorption with Langmuir adsorption capacity of 666.66 and 476.19 mg/g, respectively, at experimental condition [(pH = 6; time = 30 min; T = 45 °C, dye concentration: 500 mg/L, and adsorbent dose = 0.6 g/L for MB and 1 g/L for MV dye)]. Kinetic and isotherm models were applied to fit the experimental outcomes. The result showed that ZSCS showed an ultrafast absorption process with a high removal efficiency of MB and MV within 5 min indicating its effective adsorption properties. The Langmuir isotherm model was the most suitable model for describing the adsorption of MB and MV dyes on ZSCS. The pseudo-second-order model kinetic fits better to MB and MV adsorption onto ZSCS than other models, suggesting that the adsorption mechanism followed chemisorption. Our results could offer an efficient cost-effective approach for dye removal from wastewater.

Keywords

• Zizyphus spina-christi seeds
• Isotherm
• Methyl violet
• Methylene blue
• Mechanism