Nature Communications (Aug 2019)
Remarkable active-site dependent H2O promoting effect in CO oxidation
- Shu Zhao,
- Fang Chen,
- Sibin Duan,
- Bin Shao,
- Tianbo Li,
- Hailian Tang,
- Qingquan Lin,
- Junying Zhang,
- Lin Li,
- Jiahui Huang,
- Nicolas Bion,
- Wei Liu,
- Hui Sun,
- Ai-Qin Wang,
- Masatake Haruta,
- Botao Qiao,
- Jun Li,
- Jingyue Liu,
- Tao Zhang
Affiliations
- Shu Zhao
- Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of the Ministry of Education, Tsinghua University
- Fang Chen
- CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Sibin Duan
- Department of Physics, Arizona State University
- Bin Shao
- Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Tianbo Li
- CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Hailian Tang
- CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Qingquan Lin
- Institute of Applied Catalysis, School of Chemistry and Chemical Engineering, Yantai University
- Junying Zhang
- Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Lin Li
- CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Jiahui Huang
- Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Nicolas Bion
- Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), University of Poitiers, CNRS
- Wei Liu
- Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Hui Sun
- CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Ai-Qin Wang
- CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Masatake Haruta
- Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Botao Qiao
- Department of Physics, Arizona State University
- Jun Li
- Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of the Ministry of Education, Tsinghua University
- Jingyue Liu
- Department of Physics, Arizona State University
- Tao Zhang
- CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- DOI
- https://doi.org/10.1038/s41467-019-11871-w
- Journal volume & issue
-
Vol. 10,
no. 1
pp. 1 – 9
Abstract
The issue that whether single-atom sites possess similar catalytic properties to the interfacial sites of nanocatalysts remains unresolved. Here, the authors demonstrate a large H2O promotional effect on CO oxidation over Au single-atom sites due to their unique local atomic structure and electronic properties.
