Acta Crystallographica Section E (Dec 2013)

exo-1,7-Dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione

  • Marcos Flores-Alamo,
  • Héctor García-Ortega,
  • Laura Edith Negrete-López,
  • Oscar Fernando Vázquez-Vuelvas,
  • Armando Pineda-Contreras

DOI
https://doi.org/10.1107/S1600536813030262
Journal volume & issue
Vol. 69, no. 12
pp. o1756 – o1756

Abstract

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The title compound, C16H15NO3, consists of an oxabicycle fused to an N-phenyl-substituted pyrrolidine ring anti to the double bond, affording the exo isomer. In the oxabicycle system, the six-membered ring presents a boat conformation, while the heterocyclic rings show envelope conformations with the O atom projected out of the plane. In the crystal, adjacent molecules are linked via weak C—H...O hydrogen bonds, forming chains propagating along the a-axis direction. The chains are linked by C—H...π interactions, forming two-dimensional networks lying parallel to the ac plane.