Influence of Oxidation Level of Graphene Oxide on the Mechanical Performance and Photo-Oxidation Resistance of a Polyamide 6

Abstract

The aim of this work is to study the relationship between the chemical-physical properties of graphene oxide (GO) and the performance of a polyamide 6 (PA6) in terms of mechanical reinforcement and resistance to UV-exposure. For this purpose, two samples of GO possessing different oxidation degrees were added (0.75 wt.%) to PA6 by way of a two-step technique and the materials achieved were carefully analysed from a morphological, chemical-physical, mechanical point of view. Photo-oxidation tests were carried out to assess the performance of this class of nanohybrids after 240 h of UV-exposure. The results reveal that both nanocomposites exhibit enhanced mechanical performance and durability of PA6. However, the most oxidized GO led to a higher increase of mechanical properties and a stronger resistance to UV-exposure. All the analyses confirm that both GO samples are well dispersed and covalently attached to PA6. However, the higher the oxidation level of GO the stronger and the more extended the chemical interphase of the nanocomposite. As regards photochemical stability, both GO samples display UV-shielding capacity but the most oxidized GO also shows radical scavenging activity by virtue of its nanocavities and defects, imparted by prolonged oxidation, which endows PA6 with an outstanding durability even after 240 h of UV-exposure.

Keywords

• UV irradiation
• reactive mixing
• nanocomposites
• durability
• photo-stability
• ATR/FTIR
• photo-degradation
• radical scavenging
• antioxidant
• UV-shielding