Flotation Performance, Structure-Activity Relationship and Adsorption Mechanism of O-Isopropyl-N-Ethyl Thionocarbamate Collector for Elemental Sulfur in a High-Sulfur Residue

Abstract

O-isopropyl-N-ethyl thionocarbamate (IPETC) collector was used to selectively recover elemental sulfur from a high-sulfur residue, and its flotation performance, structure–property relationship and adsorption mechanism to elemental sulfur were studied. The raw ore flotation test showed that IPETC displayed superior flotation performance to the elemental sulfur compared with sodium ethyl xanthate (SEX) and ammonium dibutyl dithiophosphate (ADDTP) collectors. Pure mineral flotation and adsorption experiments further demonstrated that among the three collectors, IPETC had the strongest collecting power and the optimum selectivity towards elemental sulfur. The structure–property relationship research based on density functional theory (DFT) calculation supported the above conclusion. The adsorption mechanism analysis manifested that IPETC adsorption on elemental sulfur surface was a chemical process by separately generating normal covalent bond between carbonyl S atom and S atom and a backdonation covalent bond between O atom and S atom, which was confirmed by the FTIR spectrum analysis result. IPETC exhibits excellent collecting ability and selectivity for elemental sulfur and therefore it has bright application prospects.

Keywords

• O-isopropyl-N-ethyl thionocarbamate (IPETC)
• elemental sulfur
• flotation performance
• structure–property relationship
• adsorption mechanism