Determination of the mass diffusion coefficient for dried, inhomogeneous material is difficult as it depends on the drying agent temperature and the moisture content and physical structure of the material. The paper presents a method for efficient determination of the water diffusion coefficient for wood solid cuboids dried using convective drying methods. In this work, the authors define a theoretical dependence of the Fourier number on reduced water content in a convectively dried cuboidal solid, based on a simplified theoretical solution of the diffusion equation for such a body. The material for drying included shoots of common osier, robinia (false acacia), multiflora rose, and energy poplar, dried at temperatures of 40, 50, 60, 70, and 80 °C, in free convection. The obtained results differ from the theoretically anticipated changes of the coefficient.