Molecules
(May 2022)
First Trifluoromethylated Phenanthrolinediamides: Synthesis, Structure, Stereodynamics and Complexation with Ln(III)
Yuri A. Ustynyuk,
Pavel S. Lemport,
Vitaly A. Roznyatovsky,
Konstantin A. Lyssenko,
Alexey O. Gudovannyy,
Petr I. Matveev,
Ennie K. Khult,
Mariia V. Evsiunina,
Vladimir G. Petrov,
Igor P. Gloriozov,
Anton S. Pozdeev,
Valentine S. Petrov,
Nane A. Avagyan,
Alexander S. Aldoshin,
Stepan N. Kalmykov,
Valentine G. Nenajdenko
Affiliations
Yuri A. Ustynyuk
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Pavel S. Lemport
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Vitaly A. Roznyatovsky
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Konstantin A. Lyssenko
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Alexey O. Gudovannyy
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Petr I. Matveev
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Ennie K. Khult
Department of Materials Science, Moscow State University, 1-73 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Mariia V. Evsiunina
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Vladimir G. Petrov
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Igor P. Gloriozov
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Anton S. Pozdeev
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Valentine S. Petrov
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Nane A. Avagyan
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Alexander S. Aldoshin
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Stepan N. Kalmykov
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
Valentine G. Nenajdenko
Department of Chemistry, Moscow State University, 1-3 Leninskiye Gory, GSP-1, 119991 Moscow, Russia
DOI
https://doi.org/10.3390/molecules27103114
Journal volume & issue
Vol. 27,
no. 10
Abstract
Read online
The first examples of 1,10-phenanthroline-2,9-diamides bearing CF3-groups on the side amide substituents were synthesized. Due to stereoisomerism and amide rotation, such complexes have complicated behavior in solutions. Using advanced NMR techniques and X-ray analysis, their structures were completely elucidated. The possibility of the formation of complex compounds with lanthanoids nitrates was shown, and the constants of their stability are quantified. The results obtained are explained in terms of quantum-chemical calculations.
Keywords
WeChat QR code
Close
