Tris(N,N-dimethylanilinium) hexabromidostannate(IV) bromide

Abstract

In the title compound, (C8H12N)3[SnBr6]Br, the anilinium N atom of one of the three unique cations exhibits flip-flop disorder with an 0.60:0.40 occupancy ratio. In the crystal, N—H...Br hydrogen bonds link the N,N-dimethylanilinium cations and both Br− anions and [SnBr6]2− dianions into a layered arrangement parallel to (001).