Acta Crystallographica Section E (May 2009)

3,6-Dimethyl-1-phenyl-4-(2-thienyl)-8-(2-thienylmethylene)-5,6,7,8-tetrahydro-1H-pyrazolo[3,4-b][1,6]naphthyridine

  • Shujiang Tu,
  • Ning Ma,
  • Zhengguo Han,
  • Juhua Peng

DOI
https://doi.org/10.1107/S1600536809014810
Journal volume & issue
Vol. 65, no. 5
pp. o1109 – o1110

Abstract

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In the molecule of the title compound, C26H22N4S2, the pyrazole ring is oriented at a dihedral angle of 0.85 (3)° with respect to the adjacent naphthyridine ring, while the other ring of naphthyridine adopts an envelope conformation. The dihedral angle between phenyl and pyrazole rings is 87.65 (3)°. In the crystal structure, weak intermolecular C—H...N interactions link the molecules into chains. The π–π contacts between the naphthyridine rings and the naphthyridine and thiophene rings [centroid–centroid distances = 3.766 (3) and 3.878 (3) Å] may further stabilize the structure. A weak C—H...π interaction is also present.