Removal of metronidazole antibiotic from aqueous solution by ammonia-modified activated carbon: adsorption isotherm and kinetic study

Abstract

This article was aimed at investigating the removal of metronidazole (MNZ) from aquatic solutions by modified activated carbon (MAC) with amine groups. The effect of various parameters on the adsorption rate such as the initial pH, adsorbent dose and initial concentration of MNZ and contact time were scrutinized. MAC was characterized by Fourier transform infrared spectroscopy and Brunauer–Emmett–Teller techniques. The obtained results illustrated that under the optimum conditions (pH = 3, contact time = 50 min, initial MNZ concentration = 5 mg/L and MAC dose = 0.5 g/L), the maximum adsorption efficiency was 95%. Furthermore, the kinetic studies indicated the applicability of the pseudo-second-order kinetic model, whereas the adsorption isotherm fitted well with the Freundlich model (0.996), and the maximum adsorption capacity was 66.22 mg/g. The SBET and the total pure volume of MAC were 706.92 m2/g and 0.532 cm3/g, respectively. Also, the regeneration tests demonstrated that MAC had good stability after five cycles (73%). It can be concluded that MAC, as an effective adsorbent, has a high ability to remove MNZ from aqueous solutions. HIGHLIGHTS MNZ Adsorption was high in acidic conditions.; MNZ removal performance decreased with increasing initial MNZ concentration.; MNZ adsorption was well proportionated with the pseudo-second-order and Freundlich models.; MAC regeneration showed that this adsorbent has promising capacity in five regeneration cycles for MNZ removal.;

Keywords

• adsorption isotherm
• kinetic
• metronidazole antibiotic
• modified activated carbon