Acta Crystallographica Section E (Mar 2012)

1d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)

  • Regan J. Anderson,
  • Graeme J. Gainsford

DOI
https://doi.org/10.1107/S1600536812008069
Journal volume & issue
Vol. 68, no. 3
pp. o900 – o900

Abstract

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The title compound [systematic name: tetrabenzyl (1R,2R,3S,4R,5R,6S)-4-(tert-butyldiphenylsilyloxy)-3,5,6-tris(methoxymethoxy)cyclohexane-1,2-diyl bisphosphate], C56H68O15P2Si, was isolated as an intermediate in the preparation of a phosphatidylinositol phosphate for biological studies. In the crystal, the molecules are connected via one methylene C—H...π and two weak phenyl–ether C—H...O interactions. One benzyloxy group is disordered over two overlapping positions with an occupancy ratio of 0.649 (7):0.351 (7).