Acta Crystallographica Section E (Dec 2013)

[μ2-N2,N2′-Bis(3-methoxy-2-oxidobenzylidene)benzene-1,3-dicarbohydrazidato]bis[pyridinecopper(II)]

  • Zi-Jing Xiao,
  • Hai-Bin Tong

DOI
https://doi.org/10.1107/S1600536813030286
Journal volume & issue
Vol. 69, no. 12
pp. m658 – m658

Abstract

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In the centrosymmetric dinuclear title complex, [Cu2(C24H18N4O6)(C5H5N)2], the CuII ions is tetracoordinated by two O-atoms and one N-donor of the bridging terephthalohydrazonate ligand and by one pyridine N atom, resulting in a nearly square-planar N2O2 coordination geometry with the CuII ion 0.044 (2) Å out of the mean plane (r.m.s. deviation of 0.0675 Å) of the coordinating atoms.