Kinetic modeling of heterogeneous esterification reaction using initial reaction rate analysis: data extraction and evaluation of mass transfer criteria
Philippe M. Heynderickx,
Somboon Chaemchuen,
Francis Verpoort
Affiliations
Philippe M. Heynderickx
Center for Environmental and Energy Research (CEER) – Engineering of Materials via Catalysis and Characterization, Ghent University Global Campus, 119-5 Songdomunhwa-Ro, Yeonsu-Gu, Incheon, 406-840, South Korea; Department of Green Chemistry and Technology (BW24), Faculty of Bioscience Engineering, Ghent University, 653 Coupure Links, Ghent, B-9000, Belgium; Corresponding authors.
Somboon Chaemchuen
Laboratory of Organometallics, Catalysis and Ordered Materials, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, P.R. China; National Research Tomsk Polytechnic University, Lenin Avenue 30, 634050, Tomsk, Russian Federation
Francis Verpoort
Center for Environmental and Energy Research (CEER) – Engineering of Materials via Catalysis and Characterization, Ghent University Global Campus, 119-5 Songdomunhwa-Ro, Yeonsu-Gu, Incheon, 406-840, South Korea; Laboratory of Organometallics, Catalysis and Ordered Materials, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, P.R. China; National Research Tomsk Polytechnic University, Lenin Avenue 30, 634050, Tomsk, Russian Federation; Corresponding authors.
This data article provides detailed guidance to obtain heterogeneous reaction rate expressions and the corresponding initial reaction rates and their application. Explanation is provided to deal with specific criteria to rule out internal and external concentration gradients, so that the usage of intrinsic catalytic data is guaranteed. Overall, the main goal is to provide an easy tool to evaluate both aforementioned results by simple plug-and-play of available reaction data.
