Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts - Part II: Electrooxidation of H2, CO and H2/CO mixtures on well characterized PtMo

Grgur Branimir N.; Marković Nenad M.; Ross Philip N.Jr.

doi:10.2298/JSC0303191G

Journal of the Serbian Chemical Society (Jan 2003)

Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts - Part II: Electrooxidation of H2, CO and H2/CO mixtures on well characterized PtMo

Grgur Branimir N.,
Marković Nenad M.,
Ross Philip N.Jr.

Affiliations

Grgur Branimir N.: Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11001 Belgrade, Serbia and Montenegro
Marković Nenad M.: Lawrence Berkeley National Laboratory, 1 Cyclotron Road, MS 2-100, Berkeley, CA 94720, USA
Ross Philip N.Jr.: Lawrence Berkeley National Laboratory, 1 Cyclotron Road, MS 2-100, Berkeley, CA 94720, USA

DOI: https://doi.org/10.2298/JSC0303191G
Journal volume & issue: Vol. 68, no. 3
pp. 191 – 205

Abstract

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The oxidation of hydrogen and hydrogen–carbon monoxide mixture has been investigated on well-characterized metallurgically prepared platinum–molybdenum (PtMo) alloys. It was concluded that the optimum surface concentration of molybdenum is near 23 mol.%. Based on experimentally determined parameters and simulations, the mechanism of the oxidation of CO/H2 mixtures is discussed.

Published in Journal of the Serbian Chemical Society

ISSN: 0352-5139 (Print); 1820-7421 (Online)
Publisher: Serbian Chemical Society
Country of publisher: Serbia
LCC subjects: Science: Chemistry
Website: http://www.shd-pub.org.rs/index.php/JSCS

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