Regeneration of AgXO@SBA-15 for reactive adsorptive desulfurization of fuel

Abstract

Abstract Adsorbent regeneration is critical for a continuous adsorption–regeneration process and often underestimated. In this work, the regeneration of bifunctional AgXO@SBA-15 for [O]-induced reactive adsorptive desulfurization of liquid fuel is reported and further investigated. The spent AgXO@SBA-15 was regenerated in various types of solvents followed by calcination and tested in multiple desulfurization–regeneration cycles. The effects of regenerate solvents were also compared systematically. The original and regenerated AgXO@SBA-15 was characterized by X-ray diffraction, transmission electron microscopy, energy-dispersive X-ray spectroscopy, N2 adsorption, X-ray photoelectron spectroscopy and atomic absorption spectrometry. The recovery of desulfurization capacity using various solvents follows the order of acetonitrile > acetone > ethanol > methanol > water. Owing to the complete reduction of silver species to Ag0 and severe agglomeration of Ag0, the bifunctional AgXO@SBA-15 demonstrating > 85% (2.60 mg-S/g) of sulfur removal dramatically reduced to < 46% (1.56 mg-S/g) after only 1st-cycle regeneration. It is suggested that polar organic species strongly adsorbed (or residual) on the spent AgXO@SBA-15, in that case, after solvent wash may contribute to the accelerated decomposition of Ag+ to Ag0 in the following calcination step. The desulfurization capacity decreased rather mildly in the later regeneration runs. Cautious choice of regeneration conditions and strategies to rational design stabilized adsorbents is required to avert the adsorbent deactivation.

Keywords

• Bifunctional
• Regeneration
• Oxidation
• Adsorption
• Deactivation