Excess molar volume of acetonitrile + alcohol systems at 298. 15 K. - Part II: Correlation by cubic equation of state

Grgurić Ivona R.; Kijevčanin Mirjana Lj.; Đorđević Bojan D.; Tasić Aleksandar Ž.; Šerbanović Slobodan P.

doi:10.2298/JSC0301047G

Journal of the Serbian Chemical Society (Jan 2003)

Excess molar volume of acetonitrile + alcohol systems at 298. 15 K. - Part II: Correlation by cubic equation of state

Grgurić Ivona R.,
Kijevčanin Mirjana Lj.,
Đorđević Bojan D.,
Tasić Aleksandar Ž.,
Šerbanović Slobodan P.

Affiliations

Grgurić Ivona R.: Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, P. O. Box 35-03, Belgrade, Yugoslavia
Kijevčanin Mirjana Lj.: Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, P. O. Box 35-03, Belgrade, Yugoslavia
Đorđević Bojan D.: Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, P. O. Box 35-03, Belgrade, Yugoslavia
Tasić Aleksandar Ž.: Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, P. O. Box 35-03, Belgrade, Yugoslavia
Šerbanović Slobodan P.: Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, P. O. Box 35-03, Belgrade, Yugoslavia

DOI: https://doi.org/10.2298/JSC0301047G
Journal volume & issue: Vol. 68, no. 1
pp. 47 – 56

Abstract

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The excess molar volume VE of the binary liquid systems acetonitrile methanol and acetonitrile + ethanol, experimentally determined in the previous part, were correlated by the PRSV CEOS coupled with the vdW and TCBT mixing rules. The results obtained show that the number and position of the interaction parameters of these models are of great importance for a satisfactory fitting of VE data.

Published in Journal of the Serbian Chemical Society

ISSN: 0352-5139 (Print); 1820-7421 (Online)
Publisher: Serbian Chemical Society
Country of publisher: Serbia
LCC subjects: Science: Chemistry
Website: http://www.shd-pub.org.rs/index.php/JSCS

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