Performance and Mechanism of Nanoporous Ni@NiO Composites for RhB Ultrahigh Electro-Catalytic Degradation

Abstract

Today, the development of new self-supporting electrode materials with high porosity and excellent degradation properties is of great importance for the removal of dye pollutants. Herein, this work synthesized nanoporous nickel@nickel oxide (np-Ni@NiO) electrode containing an amorphous alloy in the middle interlayer. The nanoporous structure endowed the electrode with more active sites and facilitated the ion/electron transport. The electrochemical active surface area was about 185.5 cm2. The electrochemical degradation of rhodamine B (RhB) using a np-Ni@NiO electrode was systematically investigated. The effects of technology paraments (NaCl concentration, the applied potential and pH) on electro-catalytic degradation were explored. An RhB removal rate of 99.68% was achieved in 30 s at optimized conditions, which was attributed to the unique bicontinuous ligament/pore structure and more active sites on the surface, as well as lower charge transfer resistance. In addition, the degradation mechanism of RhB in electrochemical oxidation was proposed, according to active species capture tests and EPR measurements.

Keywords

• nanoporous
• Ni@NiO electrode
• electrochemical oxidation
• degradation