Micromachines (Mar 2021)

Optimal n-Type Al-Doped ZnO Overlayers for Charge Transport Enhancement in p-Type Cu<sub>2</sub>O Photocathodes

  • Hak Hyeon Lee,
  • Dong Su Kim,
  • Ji Hoon Choi,
  • Young Been Kim,
  • Sung Hyeon Jung,
  • Swagotom Sarker,
  • Nishad G. Deshpande,
  • Hee Won Suh,
  • Hyung Koun Cho

DOI
https://doi.org/10.3390/mi12030338
Journal volume & issue
Vol. 12, no. 3
p. 338

Abstract

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An effective strategy for improving the charge transport efficiency of p-type Cu2O photocathodes is the use of counter n-type semiconductors with a proper band alignment, preferably using Al-doped ZnO (AZO). Atomic layer deposition (ALD)-prepared AZO films show an increase in the built-in potential at the Cu2O/AZO interface as well as an excellent conformal coating with a thin thickness on irregular Cu2O. Considering the thin thickness of the AZO overlayers, it is expected that the composition of the Al and the layer stacking sequence in the ALD process will significantly influence the charge transport behavior and the photoelectrochemical (PEC) performance. We designed various stacking orders of AZO overlayers where the stacking layers consisted of Al2O3 (or Al) and ZnO using the atomically controlled ALD process. Al doping in ZnO results in a wide bandgap and does not degrade the absorption efficiency of Cu2O. The best PEC performance was obtained for the sample with an AZO overlayer containing conductive Al layers in the bottom and top regions. The Cu2O/AZO/TiO2/Pt photoelectrode with this overlayer exhibits an open circuit potential of 0.63 V and maintains a high cathodic photocurrent value of approximately −3.2 mA cm−2 at 0 VRHE for over 100 min.

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