Acta Crystallographica Section E (Apr 2009)

A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)]

  • Li Zhao,
  • Jian-Li Lin,
  • Wei Xu,
  • Hong-Zhen Xie

DOI
https://doi.org/10.1107/S1600536809009969
Journal volume & issue
Vol. 65, no. 4
pp. m433 – m434

Abstract

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In the title compound, [Cd(HCOO)2(C10H8N2)]n, the CdII ion, located on a position with 2.22 site symmetry, is surrounded by two 4,4′-bipyridine ligands and four formate ligands in a distorted octahedral CdN2O4 coordination. The 4,4′-bipyridine ligands bridge the metal ions, forming one-dimensional chains along different directions, which are further connected by formate ligands into a topologically (1010.124.14)(10)3 three-dimensional network.