IUCrData (Jan 2018)

(Acetamide-κO){2,2′,2′′-boranetriyltris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ4B,S,S′,S′′}copper(I) trifluoromethanesulfonate chloroform disolvate

  • Stefan Holler,
  • Ferdinand Belaj,
  • Nadia C. Mösch-Zanetti

DOI
https://doi.org/10.1107/s2414314618000378
Journal volume & issue
Vol. 3, no. 1
p. x180037

Abstract

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In the title solvated complex salt, [Cu(C27H39BN6S3)(C2H5NO)](CF3O3S)·2CHCl3, the CuI atom is coordinated by the three S atoms of the pyridazine-3-thione rings in the equatorial plane [Cu—S = 2.3072 (4)–2.3280 (4) Å] and the B atom of the scorpionate ligand and the O atom of an acetamide ligand as the apices of a trigonal bipyramid [Cu—B = 2.0456 (16) Å and Cu—O = 1.9957 (11) Å]. The amide group of the latter ligand is involved in a bifurcated hydrogen bond to the trifluoromethanesulfonate anion.

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