Química Nova (Jan 2009)

Estudo da adsorção de compostos sulfurados empregando zeólitas contendo zinco Study of adsorption of sulphur compounds employing zeolites containing zinc

  • Álvaro L. Malvesti,
  • Marcelo L. Mignoni,
  • Robison P. Scherer,
  • Fábio G. Penha,
  • Sibele B. C. Pergher

DOI
https://doi.org/10.1590/S0100-40422009000600024
Journal volume & issue
Vol. 32, no. 6
pp. 1491 – 1494

Abstract

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This paper deals with an adosrption of sulphur compounds employing zeolites containing zinc. The zeolites employed were commercial NaY and Beta. The zinc was incorporated in three levels: 0.5; 1.0 and 5%. The sulphur compounds studied were benzothiophene and dibenzothiofene. The results showed that both zeolites can be employed for adsorption of benzothiophene and dibenzothiophene. The Zn incorporation (0.5%) promotes an increase in zeolites adsorption ability. The DBT adsorbs more than BT, probably because it strongly interacts with zeolite structure. The BT adsorbs more in NaY than in beta probably because the NaY zeolite has a high intern volume. This is not observed for DBT.

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