Coordination Engineering of Ultra‐Uniform Ruthenium Nanoclusters as Efficient Multifunctional Catalysts for Zinc–Air Batteries
Yingying Guo,
Donghai Wu,
Minhan Li,
Kaixi Wang,
Shouren Zhang,
Guangli He,
Hengbo Yin,
Chenyu Huang,
Baocheng Yang,
Jianan Zhang
Affiliations
Yingying Guo
Henan Provincial Key Laboratory of Nanocomposite and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College Zhengzhou Henan 450006 P. R. China
Donghai Wu
Henan Provincial Key Laboratory of Nanocomposite and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College Zhengzhou Henan 450006 P. R. China
Minhan Li
College of Materials Science and Engineering Zhengzhou University Zhengzhou 450001 P. R. China
Kaixi Wang
Henan Provincial Key Laboratory of Nanocomposite and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College Zhengzhou Henan 450006 P. R. China
Shouren Zhang
Henan Provincial Key Laboratory of Nanocomposite and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College Zhengzhou Henan 450006 P. R. China
Guangli He
Henan Provincial Key Laboratory of Nanocomposite and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College Zhengzhou Henan 450006 P. R. China
Hengbo Yin
College of Materials Science and Engineering Zhengzhou University Zhengzhou 450001 P. R. China
Chenyu Huang
Henan Provincial Key Laboratory of Nanocomposite and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College Zhengzhou Henan 450006 P. R. China
Baocheng Yang
Henan Provincial Key Laboratory of Nanocomposite and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College Zhengzhou Henan 450006 P. R. China
Jianan Zhang
College of Materials Science and Engineering Zhengzhou University Zhengzhou 450001 P. R. China
The lack of highly efficient, inexpensive catalysts severely hinders the large‐scale application of electrochemical energy conversion technologies (e.g., electrochemical hydrogen evolution reaction (HER) for hydrogen production, metal–air batteries (Cathode: oxygen reduction reaction (ORR))). As a new class of nanomaterials with a high ratio of surface atoms and tunable composition and electronic structure, metal nanocluster (NCs) are promising candidates as catalysts. Herein, a novel catalyst using S,N‐doped carbon matrix (NSCSs) is synthesized to efficiently stabilize high density and ultra‐uniform ruthenium (Ru) nanoclusters (Ru@NSCSs) by small‐molecule self‐assembly pyrolysis approach. The obtained Ru@NSCSs catalyst exhibits outstanding HER activity in all pH conditions (especially with a low overpotential of 5 mV at a current density of 10 mA cm−2 in 1 m KOH) and excellent ORR performance (half‐wave potential (E 1/2) of 0.854 V in 0.1 m KOH). Based on the experimental investigations and theoretical calculations, it is discovered that the S‐atom can modulate the electronic structure and optimization of redox states on the surficial sites of Ru NCs during the ORR process. This work provides a feasible strategy for understanding and regulating the metal–support interface of ultra‐uniform nanoclusters catalysts.
